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Published Work
(awaiting PTW)
In the meantime, here are pdfs of a few recent Wolczanski papers
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"3-Center-4-Electron Bonding in [(silox)2Mo=NR]2(µ-Hg) Controls Reactivity while Frontier Orbitals Permit a Dimolybdenum pi-Bond Energy Estimate." Rosenfeld, D. C.; Wolczanski, P. T.; Barakat, K. A.; Buda, C.; Cundari, T. R. J. Am. Chem. Soc. 2005, 127, 8262-8263.
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"Low Coordinate Chromium Siloxides: the "Box" [Cr(µ-Cl) (µ-OSitBu3)]4, Distorted Trigonal [(tBu3SiO)Cr(µ-OSitBu3)2]Na.C6H6 and [(tBu3SiO)3Cr][Na(dibenzo-18-c-6)], and Trigonal (tBu3SiO)3Cr." Sydora, O. L.; Wolczanski, P. T.; Lobkovsky, E. B.; Buda, C.; Cundari, T. R. Inorg. Chem. 2005, 44, 2606-2618.
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"Thermodynamics, Kinetics and Mechanism of (silox)3M(olefin) to (silox)3M(alkylidene) Rearrangements (silox = tBu3SiO; M = Nb, Ta)." Hirsekorn, K. F.; Veige, A. S.; Marshak, M. P.; Koldobskaya, Y.; Wolczanski, P. T.; Cundari, T. R.; Lobkovsky, E. B. J. Am. Chem. Soc. 2005, 127, 4809-4830.
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"The Course of (R2R'SiO)3TaCl2 (R = tBu, R' = H, Me, Ph, tBu (silox); R = iPr, R' = tBu, iPr) Reduction is Dependent on Siloxide Size." Chadeayne, A. R.; Wolczanski, P. T.; Lobkovsky, E. B. Inorg. Chem. 2004, 43, 3421-3432.
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