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| Cornell Publications | |
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Y.-F. Chen, X. Serey, R. Sarkar, P. Chen, D. Erickson "Controlled photonic manipulation of proteins and other nanomaterials" Nano Letters, 2012, DOI: 10.1021/nl204561r. [pdf] |
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P. Chen "Why Nanoparticle Catalysts are Special: A Dynamic Adaptation Model" Submitted. |
| (37) |
K.-S. Han,† G. Liu,† X. Zhou, R. E. Medina, P. Chen "How does A Single Pt Nanocatalyst Behave in Two Different Reactions? A Single-Molecule Study" Nano Letters, 2012, DOI: 10.1021/nl203677b. [pdf] [Supp Info] †Equal contribution.
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X. Zhou, N. M. Andoy, G. Liu, E. Choudhary, K.-S. Han, H. Shen, P. Chen "Quantitative Super-resolution Imaging Uncovers Reactivity Patterns on Single Nanocatalysts" Nature Nanotechnology, 2012, accepted. [pdf] [Supp Info] |
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P. Chen "Solid Acid Catalysts: Stain and Shine" Nature Chemistry, 2011, 3, 839-840. [pdf] Invited News and Views article. |
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M. A. Ochoa-Daza, X. Zhou, P. Chen, R. F. Loring "Interpreting Single Turnover Catalysis Measurements with Constrained Mean Dwell Times" Journal of Chemical Physics, 2011, 135, 174509. [pdf] |
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J. J. Benitez, A. M. Keller, D. L. Huffman, L. Yatsunyk, A. C. Rosenzweig, P. Chen "Relating Dynamic Protein Interactions of Metallochaperones with Metal Transfer at the Single-Molecule Level" Faraday Discussions, 2011, 148, 71-82. [pdf] Invited contribution to the special volume: Spectroscopy, Theory and Mechanism in Bioinorganic Chemistry.
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P. Chen, X. Zhou, H. Shen, N. M. Andoy, E. Choudhary, K.-S. Han, G. Liu, W. Meng "Single-Molecule Fluorescence Imaging of Nanocatalytic Processes" Chemical Society Reviews, 2010, 39, 4560-4570. [pdf] Invited Tutorial Review to the themed issue: In-situ characterization of heterogeneous catalysts.
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H. Shen, W. Xu, P. Chen "Single-Molecule Nanoscale Electrocatalysis" Physical Chemistry Chemical Physics, 2010, 12, 6555-6563. [pdf] Invited Perspective article.
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P. Chen, N. M. Andoy, J. J. Benitez, A. M. Keller, D. Panda, F. Gao "Tackling Metal Regulation and Transport at the Single-Molecule Level" Natural Product Reports, 2010, 27, 757-767. [pdf] Invited review to the thematic issue of Metals in Cells.
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J. J. Benitez, A. M. Keller, P. Chen "Nanovesicle Trapping for Studying Weak Protein Interactions by Single-Molecule FRET" Methods in Enzymology, 2010, 472, 41-60. [pdf] Invited article to the special volume of Single Molecule Tools: Fluorescence Based Approaches.
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X. Zhou, W. Xu, G. Liu, D. Panda, P. Chen "Size Dependent Catalytic Activity and Dynamics of Gold Nanoparticles at the Single-Molecule Level" Journal of the American Chemical Society, 2010, 132, 138-146. [pdf] [Supp Info]
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W. Xu, H. Shen, G. Liu, P. Chen "Single-Molecule Kinetics of Nanoparticle Catalysis" Nano Research, 2009, 2, 911-922. [pdf] Invited review article.
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N. M. Andoy, S. K. Sarkar, Q. Wang, D. Panda, J. J. Benitez, A. Kalininskiy, P. Chen "Single-Molecule Study of Metalloregulator CueR-DNA Interactions Using Engineered Holliday Junctions" Biophysical Journal 2009, 97, 844-852. [pdf] [Supp Info] Featured on the journal cover.
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W. Xu, H. Shen, Y. J. Kim, X. Zhou, G. Liu, J. Park, P. Chen "Single-Molecule Electrocatalysis by Single-Walled Carbon Nanotubes" Nano Letters, 2009, 9, 3968–3973. [pdf] [Supp Info] Featured on the journal cover. |
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P. Chen, W. Xu, X. Zhou, D. Panda, A. Kalininskiy "Single-Nanoparticle Catalysis at Single-Turnover Resolution" Chemical Physics Letters 2009, 470, 151-157. [pdf] Invited FRONTIERS article. Featured on the journal cover.
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W. Xu, J. S. Kong, P. Chen "Probing the Catalytic Activity and Heterogeneity of Au-Nanoparticles at the Single-Molecule Level" Physical Chemistry Chemical Physics 2009, 11, 2767-2778. [pdf] |
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| (22) |
W. Xu, J. S. Kong, P. Chen "Single-Molecule Kinetic Theory of Heterogeneous and Enzyme Catalysis" Journal of Physical Chemistry C, 2009, 113, 2393-2404. [pdf] |
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P. Chen, N. M. Andoy "Single-Molecule Fluorescence Methods in Enzymology" In Comprehensive Natural
Products Chemistry II Chemistry and Biology; Mander, L., Lui, H.-W.,
Eds.; Elsevier: Oxford, 2010; Vol. 9; pp 751. [pdf] |
| (20) |
W. Xu, J. S. Kong, Y.-T. E. Yeh, P. Chen "Single-Molecule Nanocatalysis Reveals Heterogeneous Reaction Pathways and Catalytic Dynamics" Nature Materials 2008, 7, 992-996. [pdf] [Supp Info]
News highlights:
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| (19) |
J. J. Benítez, A. M. Keller, P. Ochieng, L. A. Yatsunyk, D. L. Huffman, A. C. Rosenzweig, P. Chen "Probing Transient Copper Chaperone-Wilson Disease Protein Interactions at the Single-Molecule Level with Nanovesicle Trapping" Journal of the American Chemical Society 2008, 130, 2446-2447. [pdf] [Supp Info] [Supp Info 2] Correction/Addition: J. Am. Chem. Soc. 2009, 131, 871. |
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P. Chen, N. M. Andoy "Single-Molecule Fluorescence Studies from A Bioinorganic Perspective" Inorganica Chimica Acta 2008, 361, 809-819. [pdf]
Invited contribution to the special issue in honor of Edward I.
Solomon. ![]() |
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S. K. Sarkar, N. M. Andoy, J. J. Benítez, P. R. Chen, J. S. Kong, C. He, P. Chen "Engineered Holliday Junctions as Single-Molecule Reporters for Protein-DNA Interactions with Application to a MerR-Family Regulator" Journal
of the American Chemical Society
2007, 129, 12461-12467. [pdf]
[Supp Info] ![]() |
| Postdoctoral and Graduate Publications | |
| (16) | Nan, X.; Sims, P. A.; Chen, P.; Xie, X. S. "Observation of
Individual Microtubule Motor Steps in Living Cells with Endocytosed
Quantum Dots"
J. Phys. Chem. B
2005,
109, 24220-24224. [pdf] Press highlight: "Motor steps imaged in living cells", Chemical & Engineering News, January 2, 2006, Volume 84, p22. |
| (15) | Solomon, E. I.; Basumallick, L.; Chen, P.; Kennepohl, P. "Variable Energy Photoelectron Spectroscopy: Electronic Structure and Electronic Relaxation" Coord. Chem. Rev. (Invited Issue of Synchrotron Radiation in Inorganic and Bioinorganic Chemistry), 2005, 249, 229-253. [pdf] |
| (14) | Chen, P.; Solomon, E. I., "O2 Activation by Binuclear Cu Sites: Non-Coupled versus Exchange Coupled Reaction Mechanisms" Proc. Natl. Acad. Sci. USA 2004, 101, 13105-13110. [pdf] |
| (13) | Chen, P.; Gorelsky, S. I.; Ghosh, S.; Solomon, E. I. "N2O Reduction by the m4-Sulfide Bridged Tetranuclear CuZ Cluster Active Site" Angew. Chem. Int. Ed. 2004, 43, 4132-4140. [pdf] |
| (12) | Chen, P.; Solomon, E. I., "Oxygen Activation by the Non-Coupled Binuclear Copper Site in Peptidylglycine a-Hydroxylating Monooxygenase. Reaction Mechanism and Role of the Non-Coupled Nature of the Active Site" J. Am. Chem. Soc. 2004, 126, 4991-5000. [pdf] |
| (11) | Chen, P.; Bell, P.; Eipper, B. A.; Solomon, E. I. "Oxygen Activation by the Non-Coupled Binuclear Copper Site in Peptidylglycine a-Hydroxylating Monooxygenase. Spectroscopic Definition of the Resting Sites and the Putative CuIIM-OOH Intermediate" Biochemistry 2004, 43, 5735-5747. [pdf] |
| (10) | Ghosh, S.; Gorelsky, S. I.; Chen, P.; Cabrito, I.; Moura, J. J. G.; Moura, I.; Solomon, E. I. "Activation of N2O Reduction by the Fully Reduced m4-Sulfide Bridged Tetranuclear CuZ Cluster in Nitrous Oxide Reductase" J. Am. Chem. Soc. 2003, 125, 15708-15709. [pdf] |
| (09) | Chen, P.; Fujisawa, K.; Helton, M. E.; Karlin, K. D.; Solomon, E. I. "Spectroscopy and Bonding in Side-On and End-On Cu2(S2) Cores: Comparison to Peroxide Analogues" J. Am. Chem. Soc. 2003, 125, 6394-6408. [pdf] |
| (08) | Helton, M. E.; Chen, P.; Paul, P. P.; Tyeklár, Z.; Sommer, R.; Zhakarov, L.; Rheingold, A. L.; Solomon, E. I.; Karlin, K. D. "Reaction of Elemental Sulfur with a Copper(I) Complex Forming a trans-m-1,2 End-On Disulfide Complex: New Directions in Copper-Sulfide Chemistry" J. Am. Chem. Soc. 2003, 125, 1160-1161. [pdf] |
| (07) | Chen, P.; Root, D. E.; Campochiaro, C.; Fujisawa, K.; Solomon, E. I. "Spectroscopic and Electronic Structure Studies of the Diamagnetic Side-On CuII-Superoxo Complex Cu(O2)[HB(3-R-5-iPrpz)3]: Antiferromagnetic Coupling versus Covalent Delocalization" J. Am. Chem. Soc. 2003, 125, 466-474. [pdf] |
| (06) | Chen, P.; Cabrito, I.; Moura, J. J. G.; Moura, I.; Solomon, E. I. "Spectroscopic and Electronic Structure Studies of the m4-Sulfide Bridged Tetranuclear CuZ Cluster in N2O Reductase: Molecular Insight into the Catalytic Mechanism" J. Am. Chem. Soc. 2002, 124, 10497-10507. [pdf] |
| (05) | Chen, P.; George, S. D.; Cabrito, I.; Antholine, W. E.; Moura, J. J. G.; Moura, I.; Hedman, B.; Hodgson, K. E.; Solomon, E. I. "Electronic Structure Description of the m4-Sulfide Bridged Tetranuclear CuZ Center in N2O Reductase" J. Am. Chem. Soc. 2002, 124, 744-745. [pdf] |
| (04) | Chen, P.; Solomon, E. I. "Frontier Molecular Orbital Analysis of Cun-O2 Reactivity" J. Inorg. Biochem. (Invited 30th Anniversary Issue) 2002, 88, 368-374. [pdf] |
| (03) | Chen, P.; Cabrito, I.; Antholine, W. E.; Moura, I.; Moura, J. J. G.; Solomon, E. I. "Spectroscopic Studies of the CuZ Center of Nitrous Oxide Reductase" J. Inorg. Biochem. (ICBIC10 Issue) 2001, 86, 177. |
| (02) | Solomon, E. I.; Chen, P.; Metz, M.; Lee, S. K., Palmer, A. E. "Oxygen Binding, Activation and Reduction to Water by Copper Proteins" Angew. Chem. Int. Ed. 2001, 40, 4570-4590; Angew. Chem. 2001, 113, 4702-4724. [pdf] |
| (01) | Chen, P.; Fujisawa, K.; Solomon, E. I. "Spectroscopic and Theoretical Studies of Mononuclear Copper(II) Alkyl- and Hydroperoxo Complexes: Electronic Structure Contributions to Reactivity" J. Am. Chem. Soc. 2000, 122, 10177-10193. [pdf] |


















