Publications - Coates Group
92.
"Pre-rate-determining selectivity in the terpolymerization of epoxides,
cyclic anhydrides, and CO2: a one-step route to diblock copolymers."
Jeske, Ryan C.; Rowley, John M.; Coates, Geoffrey W., Angew. Chem, Int. Ed. 2008, 47, 6041-6044.
91. "Fluorinated b-lactones and poly(b-hydroxyalkanoate)s: synthesis via epoxide carbonylation and ring-opening polymerization."
Kramer, John W.; Coates, Geoffrey W. Tetrahedron 2008, 64(29), 6973-6978.
90. "Catalytic synthesis of b3-amino acid derivatives from a-amino acids."
Byrne, Christopher M.; Church, Tamara L.; Kramer, John W.; Coates, Geoffrey W. Angew. Chem. Int. Ed. 2008, 47(21), 3979-3983.
89. "Fluorinated
Bis(phenoxyketimine)titanium Complexes for the Living, Isoselective
Polymerization of Propylene: Multiblock Isotactic Polypropylene
Copolymers via Sequential Monomer Addition."
Edson, Joseph B.; Wang, Zhigang; Kramer, Edward J.; Coates, Geoffrey W. J. Am. Chem. Soc. 2008, 130(14), 4968-4977.
88. Discrete catalysts for stereoselective epoxide polymerization.
Ajiro, Hiroharu; Allen, Scott D.; Coates, Geoffrey W. Stereoselective
Polymerization with Single-Site Catalysts (2008),
627-644.
87. "Poly(ethylene-co-propylene macromonomer)s: Synthesis and Evidence for Starlike Conformations in Dilute Solution."
Rose, Jeffrey M.; Mourey, Thomas H.; Slater, Lisa A.; Keresztes, Ivan; Fetters, Lewis J.; Coates, Geoffrey W. Macromolecules 2008, 41(3), 559-567.
86. "Carbonylation of Epoxides to Substituted 3-Hydroxy-d-Lactones."
Kramer, John W.; Joh, Daniel Y.; Coates, Geoffrey W. Org. Lett. 2007, 9(26), 5581-5583.
85. "Insight
in the role of bovine serum albumin for promoting the in situ surface
growth of polyhydroxybutyrate (PHB) on patterned surfaces via enzymatic
surface-initiated polymerization." Niamsiri, Nuttawee; Bergkvist,
Magnus; Delamarre, Soazig C.; Cady, Nathan C.; Coates, Geoffrey W.;
Ober, Christopher K.; Batt, Carl A. Colloids and Surfaces, B: Biointerfaces 2007, 60(1), 68-79.
84. "Alternating Copolymerization of Epoxides and Cyclic Anhydrides: An Improved Route to Aliphatic Polyesters."
Jeske, R. C.; DiCiccio, A. M.; Coates, G. W. J. Am. Chem. Soc. 2007, 129(37), 11330-11331.
83. "Formation of Nanoparticles by Intramolecular Cross-Linking: Following the
Reaction Progress of Single Polymer Chains by Atomic Force Microscopy"
Anna E. Cherian, A. E., Sun, F. C., Sheiko, S. S, and Coates, G. W. J. Am. Chem. Soc. 2007, 129(37), 11350-11351
82. "Analysis of Polymeric Methylaluminoxane (MAO) via Small
Angle Neutron Scattering"
Jörg
Stellbrink, J.; Niu, A.; Allgaier, J.; Richter,
D.; Koenig, B. W.; Hartmann, R.; Coates, G. W.;
and Fetters, L. J. Macromolecules; 2007; 40(14) pp
4972 - 4981.
81. "A New Multicomponent Reaction Catalyzed by a [Lewis
Acid]+[Co(CO)4]- Catalyst: Stereospecific
Synthesis of 1,3-Oxazinane-2,4-diones from Epoxides, Isocyanates, and
CO" Church, T. L.; Byrne, C. M.; Lobkovsky, E. B.; and Coates, G. W. J. Am. Chem. Soc.; 2007;
129(26) pp 8156 - 8162.
80.
“Catalytic Double Carbonylation of Epoxides to Succinic Anhydrides: Catalyst
Discovery, Reaction Scope, and Mechanism”
Rowley, J. M.; Lobkovsky, E. B.; Coates, G. W. J.
Am. Chem. Soc. 2007, 4948-4960.
79.
“Ligand Dependent Catalytic Cycle and Role of Styrene
in Nickel-Catalyzed Anhydride Cross-Coupling: Evidence for Turnover Limiting
Reductive Elimination”
Johnson, J. B.; Bercot, E. A.; Rowley, J. M.;
Coates, G. W.; Rovis, T. J. Am. Chem. Soc.
2007, 129, 2718-2725.
78. “Carbonylation of Heterocycles by Homogeneous Catalysts”
Church, T. L.; Getzler, Y. D. Y. L.; Byrne, C.
M.; Coates, G. W. Chem. Commun., 2007, 657-674.
77.
“Polymerization of a-Olefins with
Pyridylamidohafnium Catalysts: Living Behavior and Unexpected Isospecificity
from a Cs-Symmetric
Catalyst Precursor”
Domski, G. J.; Lobkovsky, E. B.; Coates, G. W. Macromolecules, 2007, 40, 3510-3513.
76.
“Coordination
Polymerization: Synthesis of New Homo- and Copolymer Architectures from
Ethylene and Propylene Using Homogeneous Ziegler-Natta Polymerization Catalysts“
Mason, A. F.; Coates, G. W. in Macromolecular Engineering: Precise
Synthesis, Materials Properties, Applications, Matyjaszewski, K.; Gnanou,
Y.; Leibler, L., eds. Wiley-VCH, Weinheim, 2007.
75.
“Living Alkene Polymerization: New Methods for the
Precision Synthesis of Polyolefins”
Domski, G. J.; Rose, J. M.; Coates, G. W.;
Bolig, A. D.; Brookhart, M. Prog.
Polym. Sci. 2007, 32, 30-92.
74.
“Semi-crystalline Thermoplastic
Elastomeric Polyolefins: Advances Through Catalyst Development and
Macromolecular Design”
Hotta, A.; Cochran, C.; Ruokolainen, J.; Khanna, V.;
Fredrickson, G. H.; Kramer, E. J.; Shin, J.-W.; Shimizu, F.; Cherian, A. E.;
Hustad, P. D.; Rose, J. M.; Coates, G. W.Proc. Nat. Acad.
Sci. 2006, 103, 15327–15332.
73. “The Mechanism of Epoxide Carbonylation by [Lewis Acid]+[Co(CO)4]-
Catalysts”
Church, T. L.; Getzler, Y. D. Y. L.; Coates, G.
W. J. Am. Chem. Soc. 2006, 128, 10125-10133.
72. “Two-Dimensional Double Metal Cyanide Complexes: Highly
Active Catalysts for the Copolymerization of Propylene Oxide and Carbon
Dioxide”
Robertson, N. J.; Qin, Z.; Lobkovsky, E. B.;
Lee, S.; Coates, G. W.Dalton Trans., 2006, 5390-5395.
71. “Alternating
Copolymerization of Propylene Oxide and Carbon Dioxide with Highly Efficient
and Selective (Salen)Co(III) Catalysts: Effect of Ligand and Cocatalyst
Variation”
Cohen, C. T.; Coates, G. W.J. Poly. Sci. Part A, 2006, 44, 5182-5191.
70. “Practical Beta-Lactone Synthesis: Epoxide
Carbonylation at 1 atm”
Kramer, J. W.; Lobkovsky, E. B.; Coates, G. W. Org. Lett. 2006, 8, 3709-3712.
69. “Living Polymerization of a-Olefins
with an a-Diimine Ni(II) Catalyst:
Formation of Well-Defined Ethylene-Propylene Copolymers through
Controlled Chain-Walking”
Rose, J. M.;
Cherian, A. E.; Coates, G. W. J. Am. Chem. Soc. 2006,
128, 4186-4187.
68. “Optically transparent and high
molecular weight polyolefin block copolymers toward self-assembled
photonic band gap materials”
Yoon, J; Mathers, R.
T.; Coates, G. W.; Thomas, E. L. Macromolecules, 2006,
39, 1913-1919.
67.
"Copolymerization of cyclohexene oxide and carbon dioxide using
(salen)Co(III) complexes: synthesis and characterization of
syndiotactic poly(cyclohexene carbonate)"
Cohen, C. T.;
Thomas, C. M.; Peretti, K. L.; Lobkovsky, E. B.; Coates, G. W. Dalton Trans. 2006, 237-249.
66. “Poly(dicyclopentadiene) submicron
fibers produced by electrospinning”
Bellan, L. M.;
Coates, G. W.; Craighead, H. G. Macromol. Rapid Commun. 2006, 27, 511-515.
65.
Real-Time Analysis of
Enzymatic Surface-Initiated Polymerization Using Surface Plasmon
Resonance (SPR)
Kim,
Y. R.; Paik, H. J.; Ober, C. K.; Coates, G. W.; Mark, S. S.; Ryan, T.
E.; Batt, C. A. Macromol. Biosci. 2006,
6,
145-152.
64. “Acid-catalyzed ortho-alkylation of anilines with styrenes: An
improved route to chiral anilines with bulky substituents”
Cherian, A. E.;
Domski, G. J.; Rose, J. M.; Lobkovsky, E. B.; Coates, G. W.
Org. Lett. 2005, 7, 5135-5137.
63.
A C2-Symmetric,
Living Alpha-Diimine Ni(II) Catalyst: Regioblock Copolymers from
Propylene
Cherian,
A. E.; Rose, J. M.; Lobkovsky, E. B.; Coates, G. W. J. Am.
Chem.
Soc. 2005, 127,
13770-13771.
62.
Chromium (III) Octaethylporphyrinato
Tetracarbonylcobaltate: A
Highly Active, Selective, and Versatile Catalyst for Epoxide
Carbonylation
Schmidt,
J. A. R.; Lobkovsky, E. B.; Coates, G. W. J. Am. Chem. Soc.
2005, 127, 11426-11435.
61.
A Highly Active,
Isospecific Cobalt Catalyst for Propylene Oxide Polymerization
Peretti,
K. L.; Ajiro, H.; Cohen, C. T.; Lobkovsky, E. B.; Coates, G. W. J.
Am. Chem. Soc. 2005, 127,
11566-11567.
60.
Cobalt Catalysts for
the Alternating Copolymerization of Propylene Oxide and Carbon
Dioxide: Combining High Activity and Selectivity
Cohen,
C. T.; Chu, T.; Coates, G. W. J. Am. Chem. Soc. 2005,
127, 10869-10878.
59.
Crystal Structure of Alternating Isotactic Ethylene-Cyclopentene
Copolymer
Auriemma,
F.; De Rosa, C.; Esposito, S.; Coates, G. W.; Fujita, M.
Macromolecules 2005, 38,
7416-7429.
58.
Synthesis of Allyl-Terminated Syndiotactic Polypropylene:
Macromonomers for the Synthesis of Branched Polyolefins
Cherian,
A. E.; Lobkovsky, E. B.; Coates, G. W. Macromolecules
2005,
38, 6259-6268.
57.
Suspended Glass Nanochannels Coupled with Microstructures for Single
Molecule Detection
Verbridge,
S. S.; Edel, J. B.; Stavis, S. M.; Moran-Mirabal, J. M.; Allen, S.
D.; Coates, G. W.; Craighead, H. G. J. Appl. Phys. 2005,
97, 124317.
56.
Dehydrogenation of aliphatic polyolefins catalyzed by pincer-ligated
iridium complexes
Ray,
A.; Zhu, K.; Kissin, Y. V.; Cherian, A. E.; Coates, G. W.; Goldman,
A. S. Chem. Commun. 2005,
3388-3390.
55.
Alternating Isotactic Ethylene-Cyclopentene Copolymer: A Crystalline
Engineering Plastomer Including High Amounts of Structural Disorder
Auriemma,
F.; De Rosa, C.; Esposito, S.; Coates, G. W.; Fujita, M. J.
Am.
Chem. Soc. 2005, 127,
2850-2851.
54.
End-functionalization of poly(3-hydroxybutyrate) via genetic
engineering for solid surface modification
Paik,
H.-J.; Kim, Y.-R.; Orth, R. N.; Ober, C. K.; Coates, G. W.; Batt, C.
A. Chem. Commun. 2005,
1956–1958.
53.
Morphology and Thermodynamic Behavior of
Syndiotactic-Polypropylene-poly(ethylene-co-propylene) Block Polymers
Prepared by Living Olefin Polymerization
Ruokolainen,
R.; Mezzenga, R.; Fredrickson, G. H.; Kramer, E. J.; Hustad, P. D.;
Coates, G. W. Macromolecules 2005,
38, 851-860.
52.
Rheological Parameters of Poly(Ethylene-co-Propylene) Copolymers
Fetters,
L. F.; Lee, J. H.; Mathers, R. T.; Hustad, P. D.; Coates, G. W.;
Archer, L. A. Macromolecules 2005,
38,
10061-10066.
51.
Synthesis of an Epoxide Carbonylation Catalyst: Exploration of
Contemporary Chemistry for Advanced Undergraduates
Getzler,
Y. D. Y. L.; Schmidt, J. A. R.; Coates, G. W. J. Chem. Ed.
2005, 82, 621-624.
50.
Carbon Dioxide as a Renewable C1 Feedstock: Synthesis and
Characterization of Polycarbonates from the Alternating
Copolymerization of Epoxides and CO2
Allen,
S. D.; Byrne, C. M.; Coates, G. W. In Feedstocks for the
Future:
Renewables for the Production of Chemicals and Materials; ACS
Symposium Series, Volume 921, Bozell, J.; Patel, Martin, Eds. ACS
Publications: Washington DC, 2005.
49.
New Phenoxyketimine Titanium Complexes: Combining Isotacticity and
Living Behavior in Propylene Polymerization
Mason,
A. F.; Coates, G. W. J. Am. Chem. Soc. 2004,
126,
16326-16327.
48.
Discrete Metal-based Catalysts for
the
Copolymerization of CO2 and Epoxides: Discovery,
Reactivity, Optimization, and Mechanism
Coates,
G. W.; Moore, D. R. Angew. Chem. Int. Ed. 2004,
43,
6618-6639.
47.
Structure and Physical Properties of Syndiotactic Polypropylene from
Living Polymerization with Bis(phenoxyimine)-Based Titanium Catalysts
De
Rosa, C.; Circelli, T.; Auriemma, F.; Mathers, R. T.; Coates, G. W.
Macromolecules 2004, 37,
9034-9047.
46.
Synthesis of Amphiphilic ABC Triblock Copolymers with PEO as the
Middle Block
Mahajan,
S.; Cho, B.-K.; Allgaier, J.; Fetters, L. J.; Coates, G. W.; Wiesner,
U. Macromol. Rapid Commun. 2004,
25, 1889-1894.
45.
Alternating Copolymerization of
Limonene Oxide
and Carbon Dioxide
Byrne,
C. M.; Allen, S. D.; Lobkovsky, E. B.; Coates, G. W. J. Am.
Chem.
Soc. 2004, 126,
11404-11405.
44.
Gel Permeation Chromatography as a
Combinatorial Screening Method: Identification of Highly Active
Hetero-Ligated Phenoxyimine Polymerization Catalysts
Mason,
A. F.; Coates, G. W. J. Am. Chem. Soc. 2004,
126,
10798-10799.
43.
Catalytic Carbonylation of beta-Lactones
to Succinic Anhydrides
Getzler,
Y. D. Y. L.; Kundnani, V. K.; Lobkovsky, E. B.; Coates, G. W. J.
Am. Chem. Soc. 2004, 126,
6842-6843.
42.
A SANS Study of the Self-Assembly in Solution of syndio-Polypropylene
Homopolymers and
syndio-Polypropylene-block-Poly(ethylene-co-Propylene)
Diblock Copolymers
Radulescu,
A; Mathers, R. T.; Coates, G. W.; Richter, D.; Fetters, L. J.
Macromolecules 2004, 37,
6962-6971.
41.
Enzymatic Surface-Initiated Polymerization: A Novel Approach for the
in Situ Solid Phase Synthesis of the Biocompatible Polymer,
Poly(3-hydroxybutyrate)
Kim,
Y.-R.; Paik, H.-J.; Ober, C. K.; Coates, G. W.; Batt, C. A.
Biomacromolecules 2004, 5,
889-894.
40.
Fabrication of blended polyphenylenevinylene nanowires by scanned
electrospinning
Kameoka,
J.; Ilic, R.; Czaplewski, D.; Mathers, R. T.; Coates, G. W.;
Craighead, H. G. J. Photopoly. Sci. Tech. 2004,
17,
421-425.
39.
Stereochemistry of Epoxide Carbonylation using Bimetallic Lewis
Acid/Metal Carbonyl Complexes
Getzler,
Y. D. Y. L.; Mahadevan, V.; Lobkovsky, E. B.; Coates, G. W. Pure
and Appl. Chem. 2004, 76,
557-564.
38.
A Readily Synthesized and Highly Active Epoxide Carbonylation
Catalyst Based on a Chromium Porphyrin Framework: Expanding the Range
of Available beta-Lactones
Schmidt,
J. A. R.; Mahadevan, V.; Getzler, Y. D. Y. L.; Coates, G. W. Org.
Lett. 2004, 6,
373-376.
37.
Cross Metathesis Functionalization of Polyolefins
Mathers,
R. T.; Coates, G. W. Chem. Comm. 2004,
422-423.
36.
Cobalt-Based Complexes for the Copolymerization of Propylene Oxide
and CO2: Active and Selective Catalysts for
Polycarbonate
Synthesis
Qin,
Z.; Thomas, C. M.; Lee, S.; Coates, G. W. Angew. Chem. Int.
Ed.
2003, 42, 5484-5487.
35.
Nanofluidic Channels with Elliptical Cross Sections Formed using a
Nonlithographic Process
Czaplewski,
D.; Kameoka, J.; Mathers, R.; Coates, G. W.; Craighead, H. G. Appl.
Phys. Lett. 2003, 83,
4836-4838.
34.
A Scanning Tip Electrospinning Source for Deposition of Oriented
Nanofibres
Kameoka,
J.; Orth, R.; Yang, Y. N.; Czaplewski, D.; Mathers, R.; Coates, G.
W.; Craighead, H. G.
Nanotechnology
2003, 14, 1124-1129.
33.
Chiral Anilines: Development of Chiral, Late-Transition Metal
Catalysts for Isospecific 2-Butene Polymerization
Cherian,
A. E.; Lobkovsky, E. B.; Coates, G. W. Chem. Comm. 2003,
2566-2567.
32.
Structure and Reactivity of Mono- and Dinuclear Diiminate Zinc Alkyl
Complexes
Allen,
S. D.; Moore, D. R.; Lobkovsky, E. B.; Coates, G. W. J.
Organomet.
Chem. 2003, 683,
137-148.
31.
Mechanism of the Alternating Copolymerization of Epoxides and CO2
using beta-Diiminate Zinc Catalysts:
Evidence for a Bimetallic Epoxide Enchainment
Moore,
D. R.; Cheng, M.; Lobkovsky, E. B.; Coates, G. W. J. Am.
Chem.
Soc. 2003, 125,
11911-11924.
30.
Highly Effective Poly(Ethylene Glycol) Ligands for Specific
Inhibition of Cell Activation by IgE Receptors
Baird,
E. J.; Holowka, D.; Coates, G. W.; Baird, B. Biochemistry
2003, 42, 12739-12748.
29.
Titanium Catalysts with Ancillary Phenoxyketimine Ligands for Living
Ethylene Polymerization
Reinartz,
S. R.; Mason, A. F.; Lobkovsky, E. B.; Coates, G. W. Organometallics
2003, 22, 2542-2544.
28.
Synthesis and Characterization of Amphiphilic Poly(ethylene
oxide)-block-Poly(hexyl methacrylate) Copolymers
Mahajan,
S.; Renker, S.; Simon, P. F. W.; Gutmann, J. S.; Jain, A.; Gruner, S.
M.; Fetters, L. J.; Coates, G. W.; Wiesner, U. Macromol.
Chem.
Phys. 2003, 204,
1047-1055.
27.
High-Activity, Single-Site Catalysts for the Alternating
Copolymerization of CO2 and Propylene Oxide
Allen,
S. D.; Moore, D. R.; Lobkovsky, E. B.; Coates, G. W. J. Am.
Chem.
Soc. 2002, 124,
14284-14285.
26.
Syndiospecific Living Catalysts for Propylene Polymerization: Effect
of Fluorination on Activity, Stereoselectivity, and Termination
Mason,
A. F.; Tian, J.; Hustad, P. D.; Lobkovsky, E. B.; Coates, G. W. Isr.
J. Chem. 2002, 42,
301-306.
25.
Synthesis and Characterization of Alternated and Multiblock
Copolymers from Ethylene and Cyclopentene
Fujita,
M.; Coates, G. W. Macromolecules 2002,
35,
9640-9647
24.
Single-Site beta-Diiminate Zinc Catalysts
for the Ring-Opening Polymerization of beta-Butyrolactone
and beta-Valerolactone to
Poly(3-Hydroxyalkanoates)
Rieth,
L. R.; Moore, D. R.; Lobkovsky, E. B.; Coates, G. W. J. Am.
Chem.
Soc. 2002, 124,
15239-15248.
23.
Insertion/Isomerization Polymerization of 1,5-Hexadiene: Synthesis of
Functional Propylene Copolymers and Block Copolymers
Hustad,
P. D.; Coates, G. W. J. Am. Chem. Soc. 2002,
124,
11578-11579.
22.
[Lewis Acid]+[Co(CO)4]-
Complexes: A
Versatile Class of Catalysts for Carbonylative Ring Expansion of
Epoxides and Aziridines
Mahadevan,
V.; Getzler, Y. D. Y. L.; Coates, G. W. Angew. Chem. Int. Ed.
2002, 41,
2781-2784.
21.
Electronic and Steric Effects on Catalysts for CO2/Epoxide
Polymerization: Subtle Modifications Resulting in Superior Activities
Moore,
D. R.; Cheng, M.; Lobkovsky, E. B.; Coates, G. W. Angew.
Chem.
Int. Ed. 2002, 41, 2599-2602.
20.
Polymerization Catalysis at the Millennium: Frontiers in
Stereoselective, Metal-Catalyzed Polymerization
Coates,
G. W. J. Chem. Soc., Dalton Trans. 2002,
467-475.
19.
Catalysts for the Living Insertion Polymerization of Alkenes: Access
to New Polyolefin Architectures Using Ziegler-Natta Chemistry
Coates,
G. W.; Hustad, P. D.; Reinartz, S. Angew. Chem. Int. Ed.
2002,
41, 2236-2257.
18.
Synthesis of beta-Lactones: A Highly Active
and Selective Catalyst for Epoxide Carbonylation
Getzler,
Y. D. Y. L.; Mahadevan, V.; Lobkovsky, E. B.; Coates, G. W. J.
Am. Chem. Soc. 2002, 124,
1174-1175.
17.
Mechanism of Propylene Insertion Using Bis(phenoxyimine)-Based
Titanium Catalysts: An Unusual Secondary Insertion of Propylene in a
Group IV Catalyst System
Hustad,
P. D.; Tian, J.; Coates, G. W. J. Am. Chem. Soc. 2002,
124, 3614-3621.
16.
Stereochemistry of Lactide Polymerization Using Chiral Catalysts: New
Opportunities for Stereocontrol using Polymer Exchange Pathways
Ovitt,
T. M.; Coates, G. W. J. Am. Chem. Soc. 2002,
124,
1316-1326.
15.
Direct Electron-Beam Patterning of Surface Coatings and Sacrificial
Layers for Micro-Total Analysis Systems
Harnett,
C. K.; Satyalakshmi, K. M.; Coates, G. W.; Craighead H. G. J.
Photopoly. Sci. Technol. 2002, 15,
493-496.
14.
Single-Site beta-Diiminate Zinc Catalysts
for the Alternating Copolymerization of CO2 and
Epoxides:
Catalyst Synthesis and Unprecedented Polymerization Activity
Cheng,
M.; Moore, D. R.; Reczek, J. R.; Chamberlain, B. M.; Lobkovsky, E.
B.; Coates, G. W. J. Am. Chem. Soc. 2001,
123,
8738-8749.
13.
Heat-Depolymerizable Polycarbonates as Electron Beam Patternable
Sacrificial Layers for Nanofluidics
Harnett,
C. K.; Coates, G. W.; Craighead H. G. J. Vac. Sci. Technol.
B,
2001, 19(6), 2842-2845.
12.
A New Catalyst for Highly Syndiospecific Living Olefin
Polymerization: Homopolymers and Block Copolymers from Ethylene and
Propylene
Tian,
J.; Hustad, P. D.; Coates, G. W. J. Am. Chem. Soc. 2001,
123, 5134-5135.
11.
Polymerization of Ureidopyrimidinone-functionalized Olefins Using
Late-transition Metal Ziegler-Natta Catalysts: Synthesis of
Thermoplastic Elastomeric Polyolefins
Rieth,
L. R.; Eaton, R. F.; Coates, G. W. Angew. Chem. Int. Ed.
2001,
40, 2153-2156.
10.
Polymerization of Lactide using Single-Site beta-Diiminate
Complexes: Stereocontrol and Mechanism
Chamberlain,
B. M.; Cheng, M.; Moore, D. R.; Ovitt, T. M.; Lobkovsky, E. B.;
Coates, G. W. J. Am. Chem. Soc. 2001,
123,
3229-3238.
9.
Enantiomerically-Enriched Organic Reagents via Polymer Synthesis:
Enantioselective Copolymerization of Cycloalkene Oxide and CO2
using Homogeneous, Zinc-based Catalysts
Cheng,
M.; Darling, N. A.; Lobkovsky, E. B.; Coates, G. W. Chem.
Comm.
2000, 2007-2008.
8.
Development of a Diversity-Based Approach for the Discovery of
Stereoselective Polymerization Catalysts: Identification of a
Catalyst for the Synthesis of Syndiotactic Polypropylene
Tian,
J.; Coates, G. W. Angew. Chem. Int. Ed. 2000,
39,
3626-3629.
7.
Stereoselective Ring-Opening Polymerization of rac-Lactide
using a Single-Site, Racemic Aluminum Alkoxide Catalyst: Synthesis of
Stereoblock Poly(lactic acid)
Ovitt,
T. M.; Coates, G. W. J. Poly. Sci., Part A 2000,
38,
4686-4692.
6.
Precise Control of Polyolefin Stereochemistry using Single-Site Metal
Catalysts
Coates,
G. W. Chem. Rev. 2000, 100,
1223-1252.
5.
Single-Site Catalysts for Ring-Opening Polymerization: Synthesis of
Heterotactic Poly(lactic acid) from rac-Lactide
Cheng,
M.; Attygalle, A. B.; Lobkovsky, E. B.; Coates, G. W. J. Am.
Chem.
Soc. 1999, 121,
11583-11584.
4.
Synthesis and Characterization of Polyolefin-Silicate Nanocomposites:
A Catalyst Intercalation and in-situ Polymerization Approach
Bergman,
J. S.; Chen, H.; Giannelis, E. P.; Thomas, M. G.; Coates, G. W.
Chem.
Commun. 1999,
2179-2180.
3.
Stereoselective Ring-Opening Polymerization of meso-Lactide:
Synthesis of Syndiotactic Poly(lactic acid)
Ovitt,
T. M.; Coates, G. W. J. Am. Chem. Soc. 1999,
121,
4072-4073.
2.
Polymerization Reactions
Coates,
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