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What are Nitrides? Why Nitrides? Challenges Synthesis Current Research Nitride Publications

Why Study Nitrides?

                    This is an important question and, of course, there is always fundamental scientific curiosity. While this is not to be minimized in graduate chemistry research, especially when we are developing new synthetic methods, one might also ask "what are nitrides good for?" To begin our answer, we note that there are many important uses of binary nitrides. These include GaN (the basis of the blue LEDs of the blu-ray player in your Playstation 3, high speed and power electronics), AlN (high thermal conductivity substrates), Si3N4 (CVD coating on electronics etc.), TiN and TaN (metallic conductors and diffusion barriers in electronics, colored surfaces in jewelery, artistic displays, etc.) NbN (thin film superconducting devices)  etc. If we look at oxide chemistry it becomes apparent that ternary and quaternary oxides offer a greater, more tunable, qualitatively different and more useful set of properties than the binaries alone. So we believe that it is reasonable to expect that ternary and quaternary nitrides will eventually provide the same, because so many useful binary nitrides are known and because we have already found structurally interesting compounds, indeed some with unusual properties. However, the study of such ternary and quaternary nitrides is still in its infancy, especially when compared to the family of oxides, or even to sulphides, phosphides, carbides etc. We have so much more to learn and that is one reason why we think that nitrides are scientifically exciting as well as being potentially technologically very interesting and useful.


TiN coatings

Above is a novel example of the coating properties when using TiN.  These are bundles of Ti wire that have reacted with nitrogen and oxygen at around 700 oC. A golden coating of TiN covers the leftmost bundle. When the other two reacted with nitrogen there was also some oxygen present. In such cases, Ti reacts with both the oxygen and nitrogen to create many different colored coatings, in this case red and blue products were formed. All these coatings are stable in air at room temperature.





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Last updated July 2007.